Unveiling the structure of a novel artificial heme-enzyme with peroxidase-like activity: A theoretical investigation
Abstract
Fe(III)-Mimochrome VI (MC6) is a recently reported artificial heme-peptide conjugate system with a high peroxidase-like activity. By design, its structure features a five-coordinated Fe(III)-deuteroporphyrin active site, embedded in a compact α-helix-heme-α-helix "sandwich" motif. Up to now, no deta …
Keywords
National Center for Biotechnology Information
NCBI
NLM
MEDLINE
pubmed abstract
nih
national institutes of health
national library of medicine
models
peptides / chemistry
Molecular*
water / chemistry
protein structure
secondary
heme / chemistry*
iron / chemistry
pmid:30091460
doi:10.1002/bip.23225
fulvio perrella
umberto raucci
nadia rega
heme / metabolism*
hydrogen bonding
molecular dynamics simulation
peroxidases / chemistry*
peroxidases / metabolism*
quantum theory
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