In this study, the influence of total suspended solids (TSS) and particle size as well as effluent temperature on peracetic acid (PAA) decomposition kinetics in municipal wastewater was investigated. PAA decomposition was best described following second order kinetics in primary effluent (PE) and first order kinetics in secondary effluent (SE) samples. For synthetic samples prepared by varying TSS levels, PAA demand increased on average by about 0.042 mg/L in PE and 0.034 mg/L in SE for every 10 mg/L increase in TSS. Similarly, the PAA decay rate constant in these samples increased at a rate of 0.0014 L/mg.min and 0.00039 min, respectively, per 10 mg/L TSS. To examine the effect of particle size, synthetic samples with narrow size fractions (20-45, 45-75, and 75-90 μm) were prepared. It was found that samples with smaller particle size fractions had a greater PAA demand and decay rate constant. Effluent temperature also enhanced the PAA decomposition rate with the calculated activation energies for PE and SE samples being 29,980 J/mol and 34,860 J/mol, respectively.